Scientists didn't discover the noble gas helium - the second most common element in the universe - on Earth until 1895. And they thought it existed in minute quantities only, until miners found a huge underground cache in Kansas in 1903.
Despite its obscurity, probably no element on the periodic table has as colorful a history as antimony. Money, madness, poison, linguistics, charlatanism, sex - pretty much every theme that runs through the periodic table can be found in Element 51.